Amino derivatives of mannuronic acid

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Amino derivatives of mannuronic acid.

The widespread occurrence of amino derivatives of the sugars in products of plant and animal origin suggests the possibility that amino derivatives of the uronic acids may likewise be of importance. The uronic acids have the characteristic structures of both aldoses and aldonic acids, and hence, like the aldoses, might be expected to yield glycosyl amines [1] and like the lactones of the aldoni...

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Amino acid derivatives with anticonvulsant activity.

A series of benzylamides of N-alkylated, N-acylated or free nine cyclic and one linear amino acids as potential anticonvulsants have been synthesized. The structures of the obtained compounds were designed on the basis of the previously determined structure and physicochemical properties/anticvonvulsant activity relationship of the formerly synthesized compounds of this type. The obtained compo...

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Chair interconversion and reactivity of mannuronic acid esters.

Mannopyranosyluronic acids display a very unusual conformation behavior in that they often prefer to adopt a (1)C4 chair conformation. They are endowed with a strikingly high reactivity when used in a glycosylation reaction as a glycosyl donor. To investigate the unusual conformational behavior a series of mannuronic acid ester derivatives, comprising anomeric triflate species and O-methyl glyc...

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ژورنال

عنوان ژورنال: Journal of Research of the National Bureau of Standards

سال: 1948

ISSN: 0091-0635

DOI: 10.6028/jres.041.003